N-Methyl-N-styrylcinnamamide (lansamide) fromClausena lansiumin Vietnam

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N-Methyl-N-styrylcinnamamide (lansamide) from Clausena lansium in Vietnam

The title compound, C(18)H(17)NO, was isolated from the seeds of Clausena lansium (wampee) (Rutaceae). The X-ray crystal structure analysis confirmed its chemical identity and revealed that it is solvent-free, in contrast to the previously reported monohydrate [Huang, Ou & Tang (2006 ▶). Acta Cryst. E62, o1987-o1988]. The mol-ecular structures are practically identical but the mol-ecules pack d...

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Crystal structures of (N-methyl-N-phenyl­amino)(N-methyl-N-phenyl­carbamoyl)sulfide and the corresponding disulfane

The title compounds, (N-methyl-N-phenyl-amino)(N-methyl-N-phenyl-car-bam-oyl)sulfide, C15H16N2OS, (I), and (N-methyl-N-phenyl-amino)-(N-methyl-N-phenyl-carbamo-yl)disulfane, C15H16N2OS2, (II), are stable derivatives of (chloro-carbon-yl)sulfenyl chloride and (chloro-carbon-yl)disulfanyl chloride, respectively. The torsion angle about the S-S bond in (II) is -92.62 (6)°, which is close to the th...

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N-{N-[N-(1,1-Dimethyl­ethoxy­carbon­yl)-l-leuc­yl]-N-methyl-l-leuc­yl}-N-methyl-l-leucine benzyl ester

The tripeptide title compound, C(32)H(53)N(3)O(6), synthesized in 80% yield by coupling of N-methyl-l-leucine benzyl ester with tert-butoxy-carbonyl-l-leucyl-N-methyl-l-leucine at 273 K, conjugates through two amide linkages and includes two protecting groups: a tert-butyl-oxycarbonyl group at the C-tip and a benzyl group at the N-tip. A classical inter-molecular N-H⋯O hydrogen bond and a weak ...

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Methyl 2-(N-methoxy­carbonyl­meth­yl-N-methylsulfamo­yl)benzoate

In the title compound, C(12)H(15)NO(6)S, the aromatic ring is oriented at dihedral angles of 64.76 (11) and 56.42 (13)° with respect to the planar methyl ester unit and the SO(2) group, respectively. The dihedral angle between the SO(2) group and the planar methoxy-carbonyl-methyl group is 50.42 (14)°. Intra-molecular C-H⋯O hydrogen bonding results in the formation of an eight-membered ring. In...

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Bis(N-methyl-N-phenyl­carbamo­yl)disulfane

The title compound, C(16)H(16)N(2)O(2)S(2), has been synthesized by several different high-yield routes, and has been encountered as a co-product in a number of reaction pathways, ever since it became of inter-est to our research program over 30 years ago. We now confirm the proposed mol-ecular structure in which the mol-ecule exhibits a twofold axis of symmetry through the mid-point of the S-S...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809009611